Oxygen subsystem in YBaCuO lattice
HTSC group
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Department of Theoretical Bases of Microelectronics
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Ioffe Institute
Results
- For experiments carried out in A.F.Ioffe PTI of RAS and Atomic Institute
of Austrian Universities the following physical models are developed:
a) model of an oxygen subsystem of thin films YBaCuO, consisting from
microcrystalline of a micron size, subjected to gamma-irradiation [1,2];
b) model of point defects evolution in YBaCuO singlecrystals subjected to
neutron irradiation and consequent annealing [3-6].
- For thin films YBaCuO, irradiated by various dozes of gamma-irradiation:
a) the defect distributions formed in oxygen subsystem during gamma
irradiation have been calculated on the base of proposed model
b) resistance vs temperature dependences R(T) (for low temperatures) of
YBaCuO films have been obtained using calculated defect concentrations;
these dependences have a satisfactory agreement with experimental results.
[1,2]
- The distributions of point defects and their clusterss in oxygen and
copper subsystems of YBaCuO singlecrystals subjected to neutron irradiation
and annealing have been obtained [3-6].
- It is shown that for small dozes of a neutron irradiation in YBaCuO
singlecrystals:
a) the critical current density Jc is proportional to average total
concentration of pinning centres < C(r) > for low magnetic fields
parallel to ab-plane [3,5].
b) critical temperature of superconducting transition Tc is proportional to
relative concentration of oxygen in Cu-O chains for low variations Tc near
to initial value [4-6].
- The numerical values of the following kinetic parameters of YBaCuO
[1-3,5] have been obtained:
- cross section for oxygen vacancy formation f by ionization for gamma -
irradiatione (3 *10-19 cm2);
- sink strength of twin boundaries in the films S = 9*1010 cm-2;
- bonding energy of oxygen with grain boundaries (1.5eV);
- dissociation energy of oxygen (E = 1.5 eV) and copper-oxygen clusterss (E
= 1.9 eV);
- activation energy of interstitial oxygen migration ab-plane (Emi =
0.8eV).
Publications
- D.V.Kulikov, R.A. Suris, Yu.V. Trushin, Physical model of the
oxygen subsystem in YBaCuO during gamma irradiation, Phys.Solid State
v.36 N10 October 1994 pp.1583-1589
A theoretical investigation is made of the influence of processes taking
place in the oxygen subsystem of thin YBaCuO films under the influence of
gamma irradiation on the value of crytical temperature of superconducting
transition and the dependence of the resistivity on the temperature.
Estimates of the numerical values are obtained for the following parameters
of oxygen subsystem of thin YBaCuO films: the sink strength, the energy of
binding of the oxygen to a sink, and the cross section for the formation of
an oxygen vacancy by ionization during gamma irradiation.
- D.V. Kulikov, R.A. Suris, J.V. Trushin. A model of interaction of oxygen
subsistem with intercristallitte boundaries in polycristalline YBaCuO film
under gamma-irradiation. Supercond. Sci. & Tehn., v.8, p.303, 1995
The influence of processes occuring in the oxygen subsystem of YBaCuO thin
films under gamma-irradiation on the critical temperature and on the
temperature dependence of the film resistance has been investigated
theoretically. The values of parameters such as sink strength values, the
energy barrier for oxygen escape from sinks and cross-section of
oxygen-vacancy formation under gamma-irradiation have been estimated.
- D.V. Kulikov, R.A. Suris, Yu.V. Trushuin, V.S. Kharlamov, D.N. Tsigankov.
Computer simulation of the annealing of point magnetic-flux pinning centers
in a neutron-irradiated YBaCuO single crystal. Tech.Phys.Lett. 22(11), 1996,
p. 920-922.
A model is presented for the evolution of point defects generated by neutron
irradiation in YBaCuO. The concentrations of point defects generated by the
neutron irradiaion are calculated. It is shown that by annealing the
irradiated sample at room temperature (in the reactor channel) it is
possible to form small clusters of point defects in concentrations
sufficient for effective pinning of the magnetic flux. This model can
explain the anisotropy in the lowering of the critical current density by
annealing of irradiated samles and shows that the critical current in the
presence of a magnetic field parallel to ab-plane is proportional to the
concentration of pinning defects
- F.M. Sauerzopf, M. Werner, H.W. Weber, R.A. Suris, D.V. Kulikov, V.S.
Kharlamov, Yu.V. Trushin, Small Defects in YBCO Single Crystals: Tc After
Neutron Irradiation and Annealing, Physica C, 282-289, p.1333-1334, (1997)
Neutron irradiation of HTCs creates a wide spectrum of defect sizes. In this
work, the influence of small defects on the critical temperature is
investigated by sequential reactor neutron irradiation and annealing of a
YBCO single crystal. The characteristic behaviour of Tc under this treatment
is satisfactorily explained by a theoretical model considering the creation,
migration and annihilation of small defects in the oxygen sublattice
- Kulikov D.V., Suris R.A., Trushin Yu.V., Kharlamov V.S., Tsigankov D.N.,
Physical model of pinning centers annealing processes in neutron irradiated
YBaCuO, Proc. of SPIE - The International Society for Optical Engeneering,
v.3345, Jan.1998, pp.241 - 248
Neutron irradiation of HTSCs creates a wide spectrum of defect sizes. In
this work, the influence of small defects on the critical temperature and
critical current density Jc is investigated. The characteristic behaviour
of Tc and Jc under this treatment is satisfactorily explained by a
theoretical model considering the creation, migration and annihilation of
small defects in the oxygen sublattice.
- D.V. Kulikov, Yu.V. Trushin, F.M. Sauerzopf, M. Zehetmayer, H.W. Weber
Changes in the transition temperature after irradiation and annealing in
single crystalline YBaCuO, submitted to Physica C
We present a model of the defect dynamics in YBaCuO crystals to understand
the changes in thr transition temperature after neutron irradiation and
subsequent annealing. These changes are closely related to the calculated
concentration of vacancies in the Cu-O chain sites.
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